1998年至2002年本科就读于西北轻工业学院（现陕西科技大学），2002年至2007年在开云平台首页 师从何仁教授从事烯烃复分解反应催化剂研究，获得博士学位。2007年末至今在开云平台首页 精细化工国家重点实验室小分子活化及催化转化团队（学术带头人吕小兵教授）从事二氧化碳资源化利用、精细化工清洁制备及绿色化学化工相关研究，其中2013年至2014年在美国科罗拉多州立大学Tomislav Rovis教授课题组作为国家公派访问学者从事合作研究。

代表性论文：

(46) Li Tao, Xiao-Fei Liu, Bai-Hao Ren, He Wang, Hui-Qin Sun, Ke Zhang, Yong-Qiang Teng, Wei-Min Ren, Xiao-Bing Lu, and Wen-Zhen Zhang*. Electroreductive Ring-Opening Carboxylation of 1,3-Oxazolidin-2-ones with CO₂ for Accessing β‑Amino Acids. Organic Letters, 2024, 26(2), 542–546. DOI: 10.1021/acs.orglett.3c04007.

(45) Xiao-Fei Liu, He Wang, Li Tao, Wei-Min Ren, Xiao-Bing Lu, Wen-Zhen Zhang*. Electrocarboxylation of Benzylic Phosphates and Phosphinates with Carbon Dioxide (Invited Paper to Special Issue Carbon Dioxide Valorization). Acta Physico-Chimica Sinica (物理化学学报), 2024, 40(9), 2307008. DOI: 10.3866/PKU.WHXB202307008.

(44) Ke Zhang, Xiao-Fei Liu, Wei-Min Ren, Xiao-Bing Lu, and Wen-Zhen Zhang*. Eletrocarboxylation Reactions Using CO₂ Both as Promoter and Carboxylative Reagent (Invited Concept Paper). Chemistry – A European Journal, 2023, 29(32), e202204073. DOI: 10.1002/chem.202204073.

(43) Lin-Lin Wang, Xiao-Fei Liu, He Wang, Li Tao, Jian Huang, Wei-Min Ren, Xiao-Bing Lu, Wen-Zhen Zhang*. Nickel-Catalyzed Electrochemical Cyclizative Carboxylation of Alkene-Tethered Carbamoyl Chlorides with Carbon Dioxide (Invited Paper to Special Issue Electrochemical Organic Synthesis). Synthesis, 2023; 55(18), 2951−2958. DOI: 10.1055/s-0041-1738439.

(42) Jian Huang, Wen-Zhen Zhang*. Electroreductive Dicarboxylation of Unactivated Skipped Dienes with CO₂ to Synthesize Cyclic Dicarboxylic Acid (Invited Highlight of Prof. Da-Gang Yu’s Angew. Chem. Int. Ed. 2023, 62, e202301892 paper). Chinese Journal of Organic Chemistry, 2023, 43(7), 2580−2581. DOI: 10.6023/cjoc202300038.

(41) Xiao-Fei Liu, Ke Zhang, Lin-Lin Wang, He Wang, Jian Huang, Xun-Ting Zhang, Xiao-Bing Lu, and Wen-Zhen Zhang*. Electroreductive Ring-Opening Carboxylation of Cycloketone Oxime Esters with Carbon Dioxide. The Journal of Organic Chemistry, 2023, 88(8), 5212−5219. DOI: 10.1021/acs.joc.2c01816.

(40) Ke Zhang, Bai-Hao Ren, Xiao-Fei Liu, Lin-Lin Wang, Min Zhang, Wei-Min Ren, Xiao-Bing Lu, and Wen-Zhen Zhang*. Direct and Selective Electrocarboxylation of Styrene Oxides with CO₂ for Accessing β-Hydroxy Acids. Angewandte Chemie International Edition, 2022, 61, e202207660. DOI: 10.1002/anie.202207660.

(39) Ke Zhang, Xiao-Fei Liu, Wen-Zhen Zhang,* Wei-Min Ren, and Xiao-Bing Lu. Electrocarboxylation of N‑Acylimines with Carbon Dioxide: Access to Substituted α‑Amino Acids. Organic Letters, 2022, 24(19), 3565−3569. DOI: 10.1021/ acs.orglett.2c01267.

(38) Xiao-Fei Liu, Ke Zhang, Li Tao, Xiao-Bing Lu, Wen-Zhen Zhang*. Recent advances in electrochemical carboxylation reactions using carbon dioxide. Green Chemical Engineering, 2022, 3(2),125-137. DOI: 10.1016/j.gce.2021.12.001.

(37) Yan-Kai Huang, Wen-Zhen Zhang,* Ke Zhang, Wen-Le Wang and Xiao-Bing Lu. Carbon dioxide-promoted palladium-catalyzed dehydration of primary allylic alcohols: access to substituted 1,3-dienes. Organic Chemistry Frontiers, 2021, 8(5), 941-946. DOI: 10.1039/d0qo01465f.

(36) Ke Zhang, Wen-Zhen Zhang*, Xue-Yan Tao, Min Zhang, Wei-Min Ren, and Xiao-Bing Lu. Carboxylative Cyclization of 2-Butenoates with Carbon Dioxide: Access to Glutaconic Anhydrides. The Journal of Organic Chemistry, 2020, 85(17), 11579-11588. DOI:10.1021/acs.joc.0c01717.

(35) Hui Zhou, Hui Zhang, Sen Mu, Wen-Zhen Zhang, Wei-Min Ren, Xiao-Bing Lu. Highly regio- and stereoselective synthesis of cyclic carbonates from biomass-derived polyols via organocatalytic cascade reaction. Green Chemistry, 2019, 21(23), 6335-6341. DOI: 10.1039/c9gc03013a.

(34) Wen-Zhen Zhang*, Yu-Qian Sun, Min Zhang, Hui Zhou, and Xiao-Bing Lu. Silver-catalyzed carboxylative cyclization of alkynic hydrazones with carbon dioxide. Chinese Journal of Catalysis, 2019, 40(8), 1153-1159. DOI: S1872-2067(19)63352-8.

(33) Wen-Zhen Zhang*, Hong-Lin Li, Yang Zeng, Xue-Yan Tao, and Xiao-Bing Lu. Palladium-catalyzed Cyclization Reaction of o-Haloanilines, CO₂ and Isocyanides: Access to Quinazoline-2,4(1H,3H)-diones. Chinese Journal of Chemistry, 2018, 36(2), 112-118. DOI: 10.1002/cjoc.201700581.

(32) Wen-Zhen Zhang*, Ning Zhang, Yu-Qian Sun, Yu-Wei Ding, and Xiao-Bing Lu. Palladium-Catalyzed Cyclization Reaction of o‑Iodoanilines, CO₂, and CO: Access to Isatoic Anhydrides. ACS Catalysis, 2017, 7(12), 8072-8076. DOI: 10.1021/acscatal.7b03000.

(31) Chun-Xiao Guo, Wen-Zhen Zhang*, Ning Zhang and Xiao-Bing Lu. 1,3-Dipolar Cycloaddition of Nitrile Imine with Carbon Dioxide: Access to 1,3,4-Oxadiazole-2(3H)-ones. The Journal of Organic Chemistry, 2017, 82(14), 7637-7642. DOI: 10.1021/acs.joc.7b00963.

(30) 张文珍^* 张 宁 郭春晓 吕小兵. 二氧化碳参与的环化反应最新研究进展. 有机化学, 2017, 37(6), 1309-1321. DOI: 10.6023/cjoc201701031.

Wen-Zhen Zhang*, Ning Zhang, Chun-Xiao Guo, and Xiao-Bing Lu. Recent Progress in the Cyclization Reactions Using Carbon Dioxide. Chinese Journal of Organic Chemistry, 2017, 37(6), 1309-1321. DOI: 10.6023/cjoc201701031.

(29) Chun-Xiao Guo, Wen-Zhen Zhang*, Hui Zhou, Ning Zhang and Xiao-Bing Lu. Access to α-Arylglycines via Umpolung Carboxylation of Aromatic Imines with Carbon Dioxide. Chemistry - A European Journal, 2016, 22(48), 17156-17159. DOI: 10.1002/chem.201604623.

(28) Wen-Zhen Zhang,* Ming-Wang Yang and Xiao-Bing Lu. Carboxylative cyclization of substituted propenyl ketones using CO₂: transition-metal-free synthesis of α-pyrones. Green Chemistry, 2016, 18(15), 4181-4184. DOI: 10.1039/c6gc01346e.

(27) Wen-Zhen Zhang,* Chun-Xiao Guo and Xiao-Bing Lu. Ni-catalyzed direct carboxylation of unactivated alkyl electrophiles with carbon dioxide. Chinese Journal of Catalysis, 2016, 37(2), 215-217. DOI: 10.1016/S1872-2067(15)61037-3.

(26) Wen-Zhen Zhang,* Ming-Wang Yang, Xu-Tong Yang, Ling-Long Shi, Hui-Bo Wang and Xiao-Bing Lu. Double carboxylation of o-alkynyl acetophenone with carbon dioxide. Organic Chemistry Frontiers, 2016, 3(2), 217-221. DOI: 10.1039/c5qo00374a.

(25) Wen-Zhen Zhang*, Silver-Catalyzed Carboxylation Reaction Using Carbon Dioxide as Carboxylative Reagent. Topics in Organometallic Chemistry, 2016, 53, 73-100. (Chapter in Carbon Dioxide and Organometallics. Edited by Xiao-Bing Lu. Springer International Publishing). DOI: 10.1007/3418_2015_96.

(24) Hui Zhou*, Guo-Xu Wang, Wen-Zhen Zhang, Xiao-Bing Lu*. CO₂ Adducts of Phosphorus Ylides: Highly Active Organocatalysts for Carbon Dioxide Transformation. ACS Catalysis, 2015, 5(11), 6773-6779. DOI: 10.1021/acscatal.5b01409.

(23) Yan-Bo Wang, Dong-Sheng Sun, Hui Zhou, Wen-Zhen Zhang, Xiao-Bing Lu. CO₂, COS and CS₂ adducts of N-heterocyclic olefins and their application as organocatalysts for carbon dioxide fixation. Green Chemistry, 2015, 17(7), 4009-4015. DOI: 10.1039/c5gc00948k.

(22) Wen-Zhen Zhang*, Si Liu and Xiao-Bing Lu. DBU-promoted carboxylative cyclization of o-hydroxy and o-acetamidoacetophenone. Beilstein Journal of Organic Chemistry, 2015, 11, 906-912. DOI: 10.3762/bjoc.11.102.

(21) Wen-Zhen Zhang,* Xiang Ren, and Xiao-Bing Lu. DBU-Mediated Carboxylative Coupling of Primary Amines, Carbon Dioxide and Propargyl Chlorides. Chinese Journal of Chemistry, 2015, 33(5), 610-613. DOI: 10.1002/cjoc.201500011.

(20) Wen-Zhen Zhang,* Tian Xia, Xu-Tong Yang and Xiao-Bing Lu. Synthesis of oxazolidine-2,4-diones by a tandem phosphorus-mediated carboxylative condensation-cyclization reaction using atmospheric carbon dioxide. Chemical Communications, 2015, 51(28), 6175-6178. DOI: 10.1039/c5cc01530h.

(19) Wen-Zhen Zhang, John C. K. Chu, Kevin M. Oberg, and Tomislav Rovis*. Enantioselective Rhodium-Catalyzed Isomerization of 4-Iminocrotonates: Asymmetric Synthesis of a Unique Chiral Synthon. Journal of the American Chemical Society, 2015, 137 (2), 553–555. DOI: 10.1021/ja510348p. Highlight by Synfacts 2015, 11(4), 0399.

(18) Yan-Bo Wang, Dong-Sheng Sun, Hui Zhou, Wen-Zhen Zhang and Xiao-Bing Lu*. Alkoxide-functionalized imidazolium betaines for CO₂ activation and catalytic transformation. Green Chemistry, 2014, 16(4), 2266-2272. DOI: 10.1039/c3gc42346h.

(17) Chuang Liu, Yi Luo,* Wenzheng Zhang,* Jingping Qu, and Xiaobing Lu. DFT Studies on the Silver-Catalyzed Carboxylation of Terminal Alkynes with CO₂: An Insight into the Catalytically Active Species. Organometallics, 2014, 33 (12), 2984–2989. DOI: 10.1021/om500086u.

(16) Wen-Zhen Zhang,* Ling-Long Shi, Chuang Liu, Xu-Tong Yang, Yan-Bo Wang, Yi Luo and Xiao-Bing Lu*. Sequential carboxylation/intramolecular cyclization reaction of o-alkynyl acetophenone with CO₂. Organic Chemistry Frontiers, 2014, 1(3), 275-283. DOI: 10.1039/c3qo00047h.

(15) Chun-Xiao Guo, Wen-Zhen Zhang,* Si Liu and Xiao-Bing Lu. Cu(I)-catalyzed Chemical Fixation of CO₂ with 2-Alkynylaniline into 4-Hydroxyquinolin-2(1H)-one. Catalysis Science & Technology, 2014, 4(6), 1570-1577. DOI: 10.1039/c3cy00858d.

(14) Yan-Bo Wang, Yi-Ming Wang, Wen-Zhen Zhang, and Xiao-Bing Lu*. Fast CO₂ Sequestration, Activation, and Catalytic Transformation Using N-Heterocyclic Olefins. Journal of the American Chemical Society, 2013, 135(32), 11996-12003. DOI: 10.1021/ja405114e.

(13) Lin-Lin Zhang, Wen-Zhen Zhang,* Ling-Long Shi, Xiang Ren, Xiao-Bing Lu*. Sequential Ag-catalyzed carboxylative coupling/Ru-catalyzed cross-metathesis reactions for the synthesis of functionalized 2-alkynoates. Chinese Journal of Catalysis, 2013, 34(6), 1179-1186. DOI: 10.1016/S1872-2067(12)60527-0.

(12) Lin-Lin Zhang, Wen-Zhen Zhang, * Xiang Ren, Xin-Yan Tan, Xiao-Bing Lu*. Synthesis of oxacyclic dienes via ring-closing enyne metathesis: difference in construction of eight-membered rings. Tetrahedron Letters, 2012, 53(26), 3389-3392. DOI: 10.1016/j.tetlet.2012.04.107.

(11) Guang-Peng Wu, Wei-Min Ren, Yi Luo, Bo Li, Wen-Zhen Zhang, and Xiao-Bing Lu*. Enhanced Asymmetric Induction for the Copolymerization of CO₂ and Cyclohexene Oxide with Unsymmetric Enantiopure SalenCo(III) Complexes: Synthesis of Crystalline CO₂-Based Polycarbonate. Journal of the American Chemical Society, 2012, 134(12), 5682-5688. DOI: 10.1021/ja300667y.

(10) Wen-Zhen Zhang,* and Xiao-Bing Lu. Synthesis of Carboxylic Acids and Derivatives Using CO₂ as Carboxylative Reagent. Chinese Journal of Catalysis, 2012, 33(5), 745-756. DOI: 10.1016/S1872-2067(11)60390-2.

(9) Xiao Zhang, Wen-Zhen Zhang,* Ling-Long Shi, Chuang Zhu, Jiao-Lai Jiang and Xiao-Bing Lu*. Ligand-free Ag(I)-catalyzed Carboxylative Coupling of Terminal Alkynes, Chloride Compounds, and CO₂. Tetrahedron, 2012, 68(44), 9085-9089. DOI: 10.1016/j.tet.2012.08.053.

(8) Xiao Zhang, Wen-Zhen Zhang,* Ling-Long Shi, Chun-Xiao Guo, Ling-Ling Zhang and Xiao-Bing Lu*. Silver(I)-Catalyzed Carboxylation of Arylboronic Esters with CO₂. Chemical Communications, 2012, 48(50), 6292-6294. DOI: 10.1039/c2cc32045b.

(7) Wen-Zhen Zhang, Xiao-Bing Lu. Chiral Salen Complexes. (Chapter 7, p257-293) in Privileged Chiral Ligands and Catalysts. Edited by Qi-Lin Zhou. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, Germany, 2011.

(6) Hui Zhou, Yi-Ming Wang, Wen-Zhen Zhang, Jing-Ping Qu and Xiao-Bing Lu*. N-Heterocyclic carbene functionalized MCM-41 as an efficient catalyst for chemical fixation of carbon dioxide. Green Chemistry, 2011, 13(3), 644-650. DOI: 10.1039/c0gc00541j.

(5) Xiao Zhang, Wen-Zhen Zhang,* Xiang Ren, Lin-Lin Zhang, and Xiao-Bing Lu*. Ligand-Free Ag(I)-Catalyzed Carboxylation of Terminal Alkynes with CO₂. Organic Letters, 2011, 13(9), 2402-2405. DOI: 10.1021/ol200638z.

(4) Wen-Zhen Zhang,* Wen-Jie Li, Xiao Zhang, Hui Zhou, and Xiao-Bing Lu*. Cu(I)-Catalyzed Carboxylative Coupling of Terminal Alkynes, Allylic Chlorides, and CO₂. 2010, Organic Letters, 12(21), 4748-4751. DOI: 10.1021/ol102172v.

(3) Ren WeiMin, Zhang WenZhen, and Lu XiaoBing*. Highly Regio- and Stereo-selective Copolymerization of CO₂ with Racemic Propylene Oxide Catalyzed by Unsymmetrical (S,S,S)-SalenCo(III) Complexes. Science China Chemistry, 2010, 53(8), 1646-1652. DOI: 10.1007/s11426-010-4049-1.

(2) Hui Zhou, Wen-Zhen Zhang, Yi-Ming Wang, Jing-Ping Qu, and Xiao-Bing Lu*. N-Heterocyclic Carbene Functionalized Polymer for Reversible Fixation-Release of CO₂. Macromolecules, 2009, 42(15), 5419-5421. DOI: 10.1021/ma901109j.

(1) Hui Zhou, Wen-Zhen Zhang, Cui-Hua Liu, Jing-Ping Qu, and Xiao-Bing Lu*. CO₂ Adducts of N-Heterocyclic Carbenes: Thermal Stability and Catalytic Activity toward the Coupling of CO₂ with Epoxides. The Journal of Organic Chemistry, 2008, 73(20), 8039-8044. DOI: 10.1021/jo801457r.

小分子活化与仿生催化